A Unified Strategy Towards N-Aryl Heterocycles by a One-Pot Copper-Catalyzed Oxidative C-H Amination of Azoles was written by Subramanian, Parthasarathi;Kaliappan, Krishna P.. And the article was included in European Journal of Organic Chemistry in 2014.Product Details of 39876-84-1 The following contents are mentioned in the article:
An efficient one-pot synthesis of N-aryl-substituted heterocycles, e.g. I (R1 = H; R12 = CH:CHCH:CH; R2 = Ph, 2-pyridyl, 4-methyl-2-pyridyl, 2-naphthyl), by a Cu-catalyzed two-fold C-N bond formation is reported. This strategy involves a CuI-catalyzed C-N bond-forming reaction between o-aminoaryl-substituted azoles, e.g. II, and electron-deficient bromoarenes R2Br followed by an intramol. sp2 C-H amination. The product I (R12 = CH:CHCH:CH; R2 = 6-methyl-2-pyridyl) thus formed has been successfully used as a ligand for the synthesis of a Pd complex. This study involved multiple reactions and reactants, such as 2-(1,2,4-Triazol-1-yl)aniline (cas: 39876-84-1Product Details of 39876-84-1).
2-(1,2,4-Triazol-1-yl)aniline (cas: 39876-84-1) belongs to triazole derivatives. Among the nitrogen-containing heterocyclic compounds, triazoles emerge with superior pharmacological applications. Triazoles are compounds with a vast spectrum of applications, varying from materials (polymers), agricultural chemicals, pharmaceuticals, photoactive chemicals and dyes.Product Details of 39876-84-1
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics