In 2018,Sciortino, Flavien; Rydzek, Gaulthier; Grasset, Fabien; Kahn, Myrtil L.; Hill, Jonathan P.; Chevance, Soizic; Gauffre, Fabienne; Ariga, Katsuhiko published 《Electro-click construction of hybrid nanocapsule films with triggered delivery properties》.Physical Chemistry Chemical Physics published the findings.HPLC of Formula: 56602-33-6 The information in the text is summarized as follows:
Hollow nanocapsules (named Hybridosomes) possessing a polymer/nanoparticle shell were used to covalently construct hybrid films in a 1-pot fashion. The alkyne bearing organic/inorganic Hybridosomes were reticulated with azide bearing homobifunctional polyethyleneglycol (PEG) linkers, by using an electro-click reaction on F-SnO2 (FTO) electrodes. The coatings were obtained by promoting the Cu(I)-catalyzed click reaction between alkyne and azide moieties in the vicinity of the electrode by the electrochem. generation of Cu(I) ions. The physicochem. properties of the covalently reticulated hybrid films obtained were studied by SEM, AFM, UV-visible and fluorescence spectroscopy. The 1-pot covalent click reaction between the nanocapsules and the PEG linkers in the film did not affect the desirable features of the Hybridosomes i.e. their hollow nanostructure their chem. versatility and their pH-sensitivity. Consequently, both the composition and the cargo-loading of the Hybridosomes films could be tuned, demonstrating the versatility of these hybrid coatings. For example, the Hybridosome films were used to encapsulate and release a bodipy fluorescent probe in response to either a pH drop or the application of an oxidative +1 V potential (vs. Ag/AgCl) at the substrate. By advancing the field of electro-synthesized films a step further toward the design of complex physicochem. interfaces, these results open perspectives for multifunctional coatings where chem. versatility, controllable stability and a hollow nanostructure are required. In addition to this study using ((1H-Benzo[d][1,2,3]triazol-1-yl)oxy)tris(dimethylamino)phosphonium hexafluorophosphate(V), there are many other studies that have used ((1H-Benzo[d][1,2,3]triazol-1-yl)oxy)tris(dimethylamino)phosphonium hexafluorophosphate(V)(cas: 56602-33-6HPLC of Formula: 56602-33-6) was used in this study.
((1H-Benzo[d][1,2,3]triazol-1-yl)oxy)tris(dimethylamino)phosphonium hexafluorophosphate(V)(cas: 56602-33-6) is a peptide coupling reagent. Can be used in the preparation of phenyl esters of amino acids which have been shown to be valuable as blocked derivatives of amino acids in the field of peptide synthesis.HPLC of Formula: 56602-33-6
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics