Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, SDS of cas: 464-48-2464-48-2, Name is (-)-Camphor, SMILES is O=C1[C@@](C2(C)C)(C)CC[C@@]2([H])C1, belongs to Triazoles compound. In a article, author is Gu, Hao, introduce new discover of the category.
Tricyclic nitrogen-rich cation salts based on 1,2,3-triazole: Chemically stable and insensitive candidates for novel gas generant
A new tricyclic nitrogen-rich compound 4,5-bis(4,5-diamine-1,2,4-triazole-3-yl)-2H-1,2,3-triazole (2) was synthesized. Monovalent and divalent cations based on 1,2,3-triazole backbone were developed for energetic salts 3-13. It is worth mentioning that energetic salt 8 was obtained as a unique zwitterionic salt. These energetic compounds exhibit good thermal stability and positive heat of formation. Most of these newly synthesized compounds were insensitive to mechanical stimulation (IS >= 24 J, FS >= 252 N), while the sensitivity of compound 4 (IS = 7 J, FS = 120 N) is similar to that of RDX (IS = 7.4 J, FS = 120 N). Additionally, crystal analysis and theoretical calculations of crystals 2, 3, 4, 8 were carried to explore the relationship between strong hydrogen bonds and physicochemical properties. Furthermore, dinitramide salt 5 and zwitterionic salt 8 have relatively high theoretical detonation properties (5: D = 8770 m s(-1), 8: D = 8545 m s(-1)), which are close to RDX (D = 8795 m s(-1)). The compounds 2-5, 8 possess outstanding combustion performance (Pmax: 4.57-13.38 MPa) tested by constant-volume combustion experiments, which are superior to frequently-used gas generant guanidine nitrate. All the results demonstrate that dinitramide salt 5 and zwitterionic salt 8 with high volumes of detonation gas (5: 826.74 L kg(-1); 8: 799.77 L kg(-1)), moderate detonation performance and appropriate mechanical sensitivities (5: IS = 28 J, FS > 360 N; 8: IS > 40 J, FS > 360 N) may be useful as novel gas generant.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 464-48-2. SDS of cas: 464-48-2.